Synthesis, Structural characterization and Exafs investigations of new ruthenium(III) complexes.
- Authors: ABBATE M; CATALDO S; FIORE T; PELLERITO C; PRINZIVALLI C; SCOPELLITI M; PELLERITO L
- Publication year: 2008
- Type: Articolo in rivista (Articolo in rivista)
- Key words: Ruthenium(III) complexes,FT-IR, ES-MS, NMR, EXAFS.
- OA Link: http://hdl.handle.net/10447/35175
Abstract
Two new complexs of Ru(III) with glucosaminic acid and 1-Methyluracil, [RuCl2(Glun-N,O)2]H (I), (Glun-= glucosaminate); [RuCl4(1-MeU-N3)(DMSO)]H2.H2O (II), (1-MeU-= 1-Methyluracilate) were prepared from the same Ru(III) precursors, RuCl3•3H2O and [(DMSO)2H][trans-RuCl4(DMSO)2]. The characterization of the complexes have been carried out by elemental analysis, FT-IR, ES-MS, NMR and EXAFS.