Preparation and structural characterization of organotin(IV) complexes with ligands containing a hetero {N} atom and a hydroxy group or hydroxy and carboxyl groups.

Abstract

Twenty-two n-butyltin(IV) and t-butyltin(IV) complexes of ligands containing an –OH (–C@O) group or –OH and –COOH groups and an aromatic {N} donor atom were prepared by metathetical reactions. On the basis of the FT-IR and Mo¨ssbauer spectroscopic data, molecular structures were assigned to these compounds. The binding sites of the ligands were identified by means of FT-IR spectroscopic measurements, and it was found that in most cases the organotin(IV) moiety reacts with the phenolic form of these ligands. In the complexes with –OH and –COOH functions, the –COOH group is coordinated to the organotin(IV) centres in a monodentate manner. The 119Sn Mo¨ssbauer and the FT-IR studies support the formation of trigonal bipyramidal (TBP) and octahedral (Oh) molecular structures. Furthermore, X-ray diffraction analysis has been performed on the n-butyltin(IV)- and t-butyltin(IV)-8-quinol 8-olato-O,N single crystals. The hexacoordinated tin centres exhibit cis-octahedral geometry in both complexes.