Unveiling the MIL-53(Al) MOF: Tuning Photoluminescence and Structural Properties via Volatile Organic Compounds Interactions
- Authors: Rehman, Tanzeel Ul; Agnello, Simonpietro; Gelardi, Franco Mario; Calvino, Martina Maria; Lazzara, Giuseppe; Buscarino, Gianpiero; Cannas, Marco
- Publication year: 2024
- Type: Articolo in rivista
- OA Link: http://hdl.handle.net/10447/631553
Abstract
MIL-53(Al) is a metal-organic framework (MOF) with unique properties, including structural flexibility, thermal stability, and luminescence. Its ability to adsorb volatile organic compounds (VOCs) and water vapor makes it a promising platform for sensing applications. This study investigated the adsorption mechanism of MIL-53(Al) with different VOCs, including ketones, alcohols, aromatics, and water molecules, focusing on structural transformations due to pore size variation and photoluminescence properties. The reported results assess MIL-53(Al) selectivity towards different VOCs and provide insights into their fundamental properties and potential applications in sensing.